1 00:00:00,350 --> 00:00:02,930 - [Instructor] So let's talk a little bit about groups 2 00:00:02,930 --> 00:00:05,890 of the periodic table. 3 00:00:05,890 --> 00:00:08,550 Now, a very simple way to think about groups 4 00:00:08,550 --> 00:00:12,210 is that they just are the columns of the periodic table, 5 00:00:12,210 --> 00:00:14,670 and standard convention is to number them. 6 00:00:14,670 --> 00:00:16,940 This is the first column, so that's group one, 7 00:00:16,940 --> 00:00:20,720 second column, third group, fourth, fifth, sixth, 8 00:00:20,720 --> 00:00:25,720 seventh, eighth, group nine, group 10, 11, 12, 9 00:00:27,860 --> 00:00:32,860 13, 14, 15, 16, 17, and 18. 10 00:00:33,870 --> 00:00:35,400 And I know some of y'all might be thinking, 11 00:00:35,400 --> 00:00:37,460 what about these f-block elements over here? 12 00:00:37,460 --> 00:00:39,400 If we were to properly do the periodic table, 13 00:00:39,400 --> 00:00:41,000 we would shift all of these, 14 00:00:41,000 --> 00:00:44,350 everything from the d-block and p-block rightwards, 15 00:00:44,350 --> 00:00:48,330 and make room for these f-block elements, 16 00:00:48,330 --> 00:00:50,950 but the convention is is that we don't number them. 17 00:00:50,950 --> 00:00:53,030 But what's interesting, why do we go through the trouble 18 00:00:53,030 --> 00:00:55,040 about calling one of these columns, 19 00:00:55,040 --> 00:00:57,960 of calling these columns a group? 20 00:00:57,960 --> 00:01:00,920 Well, this is what's interesting about the periodic table, 21 00:01:00,920 --> 00:01:03,070 is that all of the elements in a column, 22 00:01:03,070 --> 00:01:05,690 for the most part, and there's tons of exceptions, 23 00:01:05,690 --> 00:01:08,370 but for the most part, the elements in the column 24 00:01:08,370 --> 00:01:11,070 have very very very similar properties, 25 00:01:11,070 --> 00:01:13,920 and that's because the elements in a column, 26 00:01:13,920 --> 00:01:15,510 or the elements in a group, 27 00:01:15,510 --> 00:01:18,490 tend to have the same number of electrons 28 00:01:18,490 --> 00:01:19,870 in their outermost shell. 29 00:01:19,870 --> 00:01:22,530 They tend to have the same number of valence electrons, 30 00:01:22,530 --> 00:01:25,140 and valence electrons and electrons in the outermost shell, 31 00:01:25,140 --> 00:01:26,720 they tend to coincide, although, 32 00:01:26,720 --> 00:01:28,210 there's a slightly different variation. 33 00:01:28,210 --> 00:01:30,940 The valence electrons, these are the electrons 34 00:01:30,940 --> 00:01:32,800 that are going to react, 35 00:01:32,800 --> 00:01:35,690 which tend to be the outermost shell electrons, 36 00:01:35,690 --> 00:01:38,330 but there are exceptions to that, 37 00:01:38,330 --> 00:01:40,930 and there's actually a lot of interesting exceptions 38 00:01:40,930 --> 00:01:43,710 that happen in the transition metals, in the D block, 39 00:01:43,710 --> 00:01:45,310 but we're not gonna go into those details. 40 00:01:45,310 --> 00:01:46,530 Let's just think a little bit about 41 00:01:46,530 --> 00:01:49,040 some of the groups that you will hear about, 42 00:01:49,040 --> 00:01:51,860 and why they react in very similar ways. 43 00:01:51,860 --> 00:01:53,840 So if we go with group one, 44 00:01:53,840 --> 00:01:55,360 group one, and hydrogen is a little bit 45 00:01:55,360 --> 00:01:57,260 of a strange character, 46 00:01:57,260 --> 00:01:58,560 because hydrogen isn't trying to get 47 00:01:58,560 --> 00:02:00,110 to eight valence electrons, 48 00:02:00,110 --> 00:02:01,400 hydrogen in that first shell 49 00:02:01,400 --> 00:02:05,230 just wants to get to two valence electrons, like helium has, 50 00:02:05,230 --> 00:02:06,930 and so hydrogen is kind of, 51 00:02:06,930 --> 00:02:10,350 it's not, it doesn't share as much in common 52 00:02:10,350 --> 00:02:11,670 with everything else in group one 53 00:02:11,670 --> 00:02:12,910 as you might expect for, say, 54 00:02:12,910 --> 00:02:15,100 all of the things in group two. 55 00:02:15,100 --> 00:02:17,430 Group one, if you put hydrogen aside, 56 00:02:17,430 --> 00:02:21,940 these are referred to as the alkali metals, 57 00:02:21,940 --> 00:02:24,800 and hydrogen is not considered an alkali metal, 58 00:02:24,800 --> 00:02:27,423 so these right over here are the alkali, 59 00:02:28,500 --> 00:02:30,103 alkali metals. 60 00:02:31,320 --> 00:02:34,560 Now why do all of these have very similar reactions? 61 00:02:34,560 --> 00:02:36,750 Why do they have very similar properties? 62 00:02:36,750 --> 00:02:37,720 Well, to think about that, 63 00:02:37,720 --> 00:02:40,500 you just have to think about their electron configurations. 64 00:02:40,500 --> 00:02:44,710 So, for example, the electron configuration for lithium 65 00:02:44,710 --> 00:02:46,630 is going to be the same 66 00:02:46,630 --> 00:02:51,170 as the electron configuration of helium, 67 00:02:51,170 --> 00:02:53,470 of helium, and then, 68 00:02:53,470 --> 00:02:58,030 you're going to go to your second shell, 2s1. 69 00:02:58,030 --> 00:02:59,820 It has one valence electron. 70 00:02:59,820 --> 00:03:03,650 It has one electron in its outermost shell. 71 00:03:03,650 --> 00:03:04,993 What about sodium? 72 00:03:06,210 --> 00:03:09,210 Well, sodium is going to have the same 73 00:03:09,210 --> 00:03:12,003 electron configuration as neon, 74 00:03:13,260 --> 00:03:16,200 and then it's going to go 3s1, 75 00:03:16,200 --> 00:03:18,950 so once again, it has one valence electron, 76 00:03:18,950 --> 00:03:21,240 one electron in its outermost shell. 77 00:03:21,240 --> 00:03:23,780 So all of these elements in orange right over here, 78 00:03:23,780 --> 00:03:25,350 they have one valence electron, 79 00:03:25,350 --> 00:03:27,860 and they're trying to get to the octet rule, 80 00:03:27,860 --> 00:03:30,880 this kind of stable nirvana for atoms, 81 00:03:30,880 --> 00:03:33,220 and so you can imagine is that they're very reactive, 82 00:03:33,220 --> 00:03:35,190 and when they react, they tend to lose 83 00:03:35,190 --> 00:03:38,450 this electron in the outermost shell, and that is the case. 84 00:03:38,450 --> 00:03:41,860 These alkali metals are very very reactive, 85 00:03:41,860 --> 00:03:43,310 and actually, they have very similar properties. 86 00:03:43,310 --> 00:03:46,790 They're shiny and soft, and actually, 87 00:03:46,790 --> 00:03:47,960 because they're so reactive, 88 00:03:47,960 --> 00:03:49,600 it's hard to find them where they haven't 89 00:03:49,600 --> 00:03:51,530 reacted with other things. 90 00:03:51,530 --> 00:03:53,960 Well, let's keep looking at the other groups. 91 00:03:53,960 --> 00:03:57,410 Well, if we move one over to the right, 92 00:03:57,410 --> 00:04:00,410 this group two right over here, 93 00:04:00,410 --> 00:04:03,353 these are called the alkaline earth metals. 94 00:04:04,266 --> 00:04:09,266 Alkaline, alkaline earth metals. 95 00:04:09,340 --> 00:04:13,880 And once again, they have very similar properties, 96 00:04:13,880 --> 00:04:16,380 and that's because they have two valence electrons, 97 00:04:16,380 --> 00:04:19,350 two electrons in their outermost shell, 98 00:04:19,350 --> 00:04:21,960 and also for them, not quite as reactive 99 00:04:21,960 --> 00:04:23,570 as the alkali metals, 100 00:04:23,570 --> 00:04:27,420 but let me write this, alkaline earth metals, 101 00:04:27,420 --> 00:04:29,640 but for them it's easier to lose two electrons 102 00:04:29,640 --> 00:04:31,860 than to try to gain six to get to eight, 103 00:04:31,860 --> 00:04:34,470 and so these tend to also be reasonably reactive, 104 00:04:34,470 --> 00:04:38,920 and they react by losing those two outer electrons. 105 00:04:38,920 --> 00:04:42,710 Now something interesting happens as you go to the D-block, 106 00:04:42,710 --> 00:04:44,510 and we studied this when we looked 107 00:04:44,510 --> 00:04:46,270 at electron configurations, 108 00:04:46,270 --> 00:04:48,430 but if you look at the electron configuration 109 00:04:48,430 --> 00:04:51,250 for say, scandium right over here, 110 00:04:51,250 --> 00:04:54,350 the electron, let me do it in magenta, 111 00:04:54,350 --> 00:04:57,420 the electron configuration for scandium, 112 00:04:57,420 --> 00:04:58,823 so scandium, 113 00:05:01,070 --> 00:05:02,430 scandium's electron configuration 114 00:05:02,430 --> 00:05:06,080 is going to be the same as argon, 115 00:05:06,080 --> 00:05:08,170 it's going to be argon. 116 00:05:08,170 --> 00:05:10,300 The aufbau principle would tell us 117 00:05:10,300 --> 00:05:12,150 that the electron configuration, 118 00:05:12,150 --> 00:05:15,860 we would have the 4s2 just like calcium, 119 00:05:15,860 --> 00:05:17,520 but by the aufbau principle, 120 00:05:17,520 --> 00:05:21,400 we would also have one electron in 3d. 121 00:05:21,400 --> 00:05:24,843 So it would be argon, then 3d1 4s2. 122 00:05:27,280 --> 00:05:30,670 And to get things in the right order for our shells, 123 00:05:30,670 --> 00:05:34,510 let me put the 3d1 before the 4s2. 124 00:05:34,510 --> 00:05:37,320 And so when people think about the aufbau principle, 125 00:05:37,320 --> 00:05:40,300 they imagine all of these d-block elements 126 00:05:40,300 --> 00:05:43,000 as somehow filling the d-block. 127 00:05:43,000 --> 00:05:45,980 Now as we know in other videos, that's not exactly true, 128 00:05:45,980 --> 00:05:49,340 but when you're conceptualizing the electron configuration 129 00:05:49,340 --> 00:05:51,270 it might be useful. 130 00:05:51,270 --> 00:05:54,600 Then you come over here and you start filling the p-block. 131 00:05:54,600 --> 00:05:59,240 So for example, if you look at the electron configuration 132 00:05:59,240 --> 00:06:01,810 for, let's say carbon, 133 00:06:01,810 --> 00:06:05,930 carbon is going to have the same electron configuration 134 00:06:05,930 --> 00:06:09,410 as helium, as helium, 135 00:06:09,410 --> 00:06:12,450 and then you're going to fill your s-block 2s2, 136 00:06:12,450 --> 00:06:13,503 and then 2p one 2. 137 00:06:15,695 --> 00:06:17,590 So 2p2. 138 00:06:17,590 --> 00:06:19,600 So how many valence electrons does it have? 139 00:06:19,600 --> 00:06:21,700 Well, in its second shell, its outermost shell, 140 00:06:21,700 --> 00:06:24,890 it has two plus two, it has four valence electrons, 141 00:06:24,890 --> 00:06:28,180 and that's going to be true for the things in this group, 142 00:06:28,180 --> 00:06:29,340 and because of that, 143 00:06:29,340 --> 00:06:34,120 carbon has similar bonding behavior to silicon, 144 00:06:34,120 --> 00:06:36,120 to the other things in its group. 145 00:06:36,120 --> 00:06:38,630 And we can keep going on, you know, 146 00:06:38,630 --> 00:06:42,730 for example, oxygen, oxygen and sulfur, 147 00:06:42,730 --> 00:06:45,840 these would both want to take two electrons 148 00:06:45,840 --> 00:06:48,620 from someone else because they have six valence electrons, 149 00:06:48,620 --> 00:06:49,550 they want to get to eight, 150 00:06:49,550 --> 00:06:51,580 so they have similar bonding behavior. 151 00:06:51,580 --> 00:06:53,440 You go to this yellow group right over here, 152 00:06:53,440 --> 00:06:55,490 these are the halogens. 153 00:06:55,490 --> 00:06:57,100 So there's a special name for them. 154 00:06:57,100 --> 00:06:59,650 These are the halogens. 155 00:06:59,650 --> 00:07:01,250 And these are highly reactive, 156 00:07:01,250 --> 00:07:03,030 because they have seven valence electrons. 157 00:07:03,030 --> 00:07:03,960 They would love nothing more 158 00:07:03,960 --> 00:07:06,250 than to get one more valence electron, 159 00:07:06,250 --> 00:07:07,610 so they love to react, in fact, 160 00:07:07,610 --> 00:07:09,080 they especially love to react 161 00:07:09,080 --> 00:07:11,850 with the alkali metals over here. 162 00:07:11,850 --> 00:07:16,150 And then finally, you get to kind of your atomic nirvana 163 00:07:16,150 --> 00:07:18,520 in the noble gases here. 164 00:07:18,520 --> 00:07:20,900 And so the noble gases, that's the other name 165 00:07:20,900 --> 00:07:25,900 for the group 18 elements, noble gases. 166 00:07:26,030 --> 00:07:28,560 And they all have the very similar property 167 00:07:28,560 --> 00:07:29,710 of not being reactive. 168 00:07:29,710 --> 00:07:30,740 Why don't they react? 169 00:07:30,740 --> 00:07:32,600 They have filled their outermost shell. 170 00:07:32,600 --> 00:07:34,220 They don't find the need, they're noble, 171 00:07:34,220 --> 00:07:35,560 they're kind of above the fray, 172 00:07:35,560 --> 00:07:40,513 they don't find the need to have to react with anyone else.