WEBVTT 00:00:00.350 --> 00:00:02.930 - [Instructor] So let's talk a little bit about groups 00:00:02.930 --> 00:00:05.890 of the periodic table. 00:00:05.890 --> 00:00:08.550 Now, a very simple way to think about groups 00:00:08.550 --> 00:00:12.210 is that they just are the columns of the periodic table, 00:00:12.210 --> 00:00:14.670 and standard convention is to number them. 00:00:14.670 --> 00:00:16.940 This is the first column, so that's group one, 00:00:16.940 --> 00:00:20.720 second column, third group, fourth, fifth, sixth, 00:00:20.720 --> 00:00:25.720 seventh, eighth, group nine, group 10, 11, 12, 00:00:27.860 --> 00:00:32.860 13, 14, 15, 16, 17, and 18. 00:00:33.870 --> 00:00:35.400 And I know some of y'all might be thinking, 00:00:35.400 --> 00:00:37.460 what about these f-block elements over here? 00:00:37.460 --> 00:00:39.400 If we were to properly do the periodic table, 00:00:39.400 --> 00:00:41.000 we would shift all of these, 00:00:41.000 --> 00:00:44.350 everything from the d-block and p-block rightwards, 00:00:44.350 --> 00:00:48.330 and make room for these f-block elements, 00:00:48.330 --> 00:00:50.950 but the convention is is that we don't number them. 00:00:50.950 --> 00:00:53.030 But what's interesting, why do we go through the trouble 00:00:53.030 --> 00:00:55.040 about calling one of these columns, 00:00:55.040 --> 00:00:57.960 of calling these columns a group? 00:00:57.960 --> 00:01:00.920 Well, this is what's interesting about the periodic table, 00:01:00.920 --> 00:01:03.070 is that all of the elements in a column, 00:01:03.070 --> 00:01:05.690 for the most part, and there's tons of exceptions, 00:01:05.690 --> 00:01:08.370 but for the most part, the elements in the column 00:01:08.370 --> 00:01:11.070 have very very very similar properties, 00:01:11.070 --> 00:01:13.920 and that's because the elements in a column, 00:01:13.920 --> 00:01:15.510 or the elements in a group, 00:01:15.510 --> 00:01:18.490 tend to have the same number of electrons 00:01:18.490 --> 00:01:19.870 in their outermost shell. 00:01:19.870 --> 00:01:22.530 They tend to have the same number of valence electrons, 00:01:22.530 --> 00:01:25.140 and valence electrons and electrons in the outermost shell, 00:01:25.140 --> 00:01:26.720 they tend to coincide, although, 00:01:26.720 --> 00:01:28.210 there's a slightly different variation. 00:01:28.210 --> 00:01:30.940 The valence electrons, these are the electrons 00:01:30.940 --> 00:01:32.800 that are going to react, 00:01:32.800 --> 00:01:35.690 which tend to be the outermost shell electrons, 00:01:35.690 --> 00:01:38.330 but there are exceptions to that, 00:01:38.330 --> 00:01:40.930 and there's actually a lot of interesting exceptions 00:01:40.930 --> 00:01:43.710 that happen in the transition metals, in the D block, 00:01:43.710 --> 00:01:45.310 but we're not gonna go into those details. 00:01:45.310 --> 00:01:46.530 Let's just think a little bit about 00:01:46.530 --> 00:01:49.040 some of the groups that you will hear about, 00:01:49.040 --> 00:01:51.860 and why they react in very similar ways. 00:01:51.860 --> 00:01:53.840 So if we go with group one, 00:01:53.840 --> 00:01:55.360 group one, and hydrogen is a little bit 00:01:55.360 --> 00:01:57.260 of a strange character, 00:01:57.260 --> 00:01:58.560 because hydrogen isn't trying to get 00:01:58.560 --> 00:02:00.110 to eight valence electrons, 00:02:00.110 --> 00:02:01.400 hydrogen in that first shell 00:02:01.400 --> 00:02:05.230 just wants to get to two valence electrons, like helium has, 00:02:05.230 --> 00:02:06.930 and so hydrogen is kind of, 00:02:06.930 --> 00:02:10.350 it's not, it doesn't share as much in common 00:02:10.350 --> 00:02:11.670 with everything else in group one 00:02:11.670 --> 00:02:12.910 as you might expect for, say, 00:02:12.910 --> 00:02:15.100 all of the things in group two. 00:02:15.100 --> 00:02:17.430 Group one, if you put hydrogen aside, 00:02:17.430 --> 00:02:21.940 these are referred to as the alkali metals, 00:02:21.940 --> 00:02:24.800 and hydrogen is not considered an alkali metal, 00:02:24.800 --> 00:02:27.423 so these right over here are the alkali, 00:02:28.500 --> 00:02:30.103 alkali metals. 00:02:31.320 --> 00:02:34.560 Now why do all of these have very similar reactions? 00:02:34.560 --> 00:02:36.750 Why do they have very similar properties? 00:02:36.750 --> 00:02:37.720 Well, to think about that, 00:02:37.720 --> 00:02:40.500 you just have to think about their electron configurations. 00:02:40.500 --> 00:02:44.710 So, for example, the electron configuration for lithium 00:02:44.710 --> 00:02:46.630 is going to be the same 00:02:46.630 --> 00:02:51.170 as the electron configuration of helium, 00:02:51.170 --> 00:02:53.470 of helium, and then, 00:02:53.470 --> 00:02:58.030 you're going to go to your second shell, 2s1. 00:02:58.030 --> 00:02:59.820 It has one valence electron. 00:02:59.820 --> 00:03:03.650 It has one electron in its outermost shell. 00:03:03.650 --> 00:03:04.993 What about sodium? 00:03:06.210 --> 00:03:09.210 Well, sodium is going to have the same 00:03:09.210 --> 00:03:12.003 electron configuration as neon, 00:03:13.260 --> 00:03:16.200 and then it's going to go 3s1, 00:03:16.200 --> 00:03:18.950 so once again, it has one valence electron, 00:03:18.950 --> 00:03:21.240 one electron in its outermost shell. 00:03:21.240 --> 00:03:23.780 So all of these elements in orange right over here, 00:03:23.780 --> 00:03:25.350 they have one valence electron, 00:03:25.350 --> 00:03:27.860 and they're trying to get to the octet rule, 00:03:27.860 --> 00:03:30.880 this kind of stable nirvana for atoms, 00:03:30.880 --> 00:03:33.220 and so you can imagine is that they're very reactive, 00:03:33.220 --> 00:03:35.190 and when they react, they tend to lose 00:03:35.190 --> 00:03:38.450 this electron in the outermost shell, and that is the case. 00:03:38.450 --> 00:03:41.860 These alkali metals are very very reactive, 00:03:41.860 --> 00:03:43.310 and actually, they have very similar properties. 00:03:43.310 --> 00:03:46.790 They're shiny and soft, and actually, 00:03:46.790 --> 00:03:47.960 because they're so reactive, 00:03:47.960 --> 00:03:49.600 it's hard to find them where they haven't 00:03:49.600 --> 00:03:51.530 reacted with other things. 00:03:51.530 --> 00:03:53.960 Well, let's keep looking at the other groups. 00:03:53.960 --> 00:03:57.410 Well, if we move one over to the right, 00:03:57.410 --> 00:04:00.410 this group two right over here, 00:04:00.410 --> 00:04:03.353 these are called the alkaline earth metals. 00:04:04.266 --> 00:04:09.266 Alkaline, alkaline earth metals. 00:04:09.340 --> 00:04:13.880 And once again, they have very similar properties, 00:04:13.880 --> 00:04:16.380 and that's because they have two valence electrons, 00:04:16.380 --> 00:04:19.350 two electrons in their outermost shell, 00:04:19.350 --> 00:04:21.960 and also for them, not quite as reactive 00:04:21.960 --> 00:04:23.570 as the alkali metals, 00:04:23.570 --> 00:04:27.420 but let me write this, alkaline earth metals, 00:04:27.420 --> 00:04:29.640 but for them it's easier to lose two electrons 00:04:29.640 --> 00:04:31.860 than to try to gain six to get to eight, 00:04:31.860 --> 00:04:34.470 and so these tend to also be reasonably reactive, 00:04:34.470 --> 00:04:38.920 and they react by losing those two outer electrons. 00:04:38.920 --> 00:04:42.710 Now something interesting happens as you go to the D-block, 00:04:42.710 --> 00:04:44.510 and we studied this when we looked 00:04:44.510 --> 00:04:46.270 at electron configurations, 00:04:46.270 --> 00:04:48.430 but if you look at the electron configuration 00:04:48.430 --> 00:04:51.250 for say, scandium right over here, 00:04:51.250 --> 00:04:54.350 the electron, let me do it in magenta, 00:04:54.350 --> 00:04:57.420 the electron configuration for scandium, 00:04:57.420 --> 00:04:58.823 so scandium, 00:05:01.070 --> 00:05:02.430 scandium's electron configuration 00:05:02.430 --> 00:05:06.080 is going to be the same as argon, 00:05:06.080 --> 00:05:08.170 it's going to be argon. 00:05:08.170 --> 00:05:10.300 The aufbau principle would tell us 00:05:10.300 --> 00:05:12.150 that the electron configuration, 00:05:12.150 --> 00:05:15.860 we would have the 4s2 just like calcium, 00:05:15.860 --> 00:05:17.520 but by the aufbau principle, 00:05:17.520 --> 00:05:21.400 we would also have one electron in 3d. 00:05:21.400 --> 00:05:24.843 So it would be argon, then 3d1 4s2. 00:05:27.280 --> 00:05:30.670 And to get things in the right order for our shells, 00:05:30.670 --> 00:05:34.510 let me put the 3d1 before the 4s2. 00:05:34.510 --> 00:05:37.320 And so when people think about the aufbau principle, 00:05:37.320 --> 00:05:40.300 they imagine all of these d-block elements 00:05:40.300 --> 00:05:43.000 as somehow filling the d-block. 00:05:43.000 --> 00:05:45.980 Now as we know in other videos, that's not exactly true, 00:05:45.980 --> 00:05:49.340 but when you're conceptualizing the electron configuration 00:05:49.340 --> 00:05:51.270 it might be useful. 00:05:51.270 --> 00:05:54.600 Then you come over here and you start filling the p-block. 00:05:54.600 --> 00:05:59.240 So for example, if you look at the electron configuration 00:05:59.240 --> 00:06:01.810 for, let's say carbon, 00:06:01.810 --> 00:06:05.930 carbon is going to have the same electron configuration 00:06:05.930 --> 00:06:09.410 as helium, as helium, 00:06:09.410 --> 00:06:12.450 and then you're going to fill your s-block 2s2, 00:06:12.450 --> 00:06:13.503 and then 2p one 2. 00:06:15.695 --> 00:06:17.590 So 2p2. 00:06:17.590 --> 00:06:19.600 So how many valence electrons does it have? 00:06:19.600 --> 00:06:21.700 Well, in its second shell, its outermost shell, 00:06:21.700 --> 00:06:24.890 it has two plus two, it has four valence electrons, 00:06:24.890 --> 00:06:28.180 and that's going to be true for the things in this group, 00:06:28.180 --> 00:06:29.340 and because of that, 00:06:29.340 --> 00:06:34.120 carbon has similar bonding behavior to silicon, 00:06:34.120 --> 00:06:36.120 to the other things in its group. 00:06:36.120 --> 00:06:38.630 And we can keep going on, you know, 00:06:38.630 --> 00:06:42.730 for example, oxygen, oxygen and sulfur, 00:06:42.730 --> 00:06:45.840 these would both want to take two electrons 00:06:45.840 --> 00:06:48.620 from someone else because they have six valence electrons, 00:06:48.620 --> 00:06:49.550 they want to get to eight, 00:06:49.550 --> 00:06:51.580 so they have similar bonding behavior. 00:06:51.580 --> 00:06:53.440 You go to this yellow group right over here, 00:06:53.440 --> 00:06:55.490 these are the halogens. 00:06:55.490 --> 00:06:57.100 So there's a special name for them. 00:06:57.100 --> 00:06:59.650 These are the halogens. 00:06:59.650 --> 00:07:01.250 And these are highly reactive, 00:07:01.250 --> 00:07:03.030 because they have seven valence electrons. 00:07:03.030 --> 00:07:03.960 They would love nothing more 00:07:03.960 --> 00:07:06.250 than to get one more valence electron, 00:07:06.250 --> 00:07:07.610 so they love to react, in fact, 00:07:07.610 --> 00:07:09.080 they especially love to react 00:07:09.080 --> 00:07:11.850 with the alkali metals over here. 00:07:11.850 --> 00:07:16.150 And then finally, you get to kind of your atomic nirvana 00:07:16.150 --> 00:07:18.520 in the noble gases here. 00:07:18.520 --> 00:07:20.900 And so the noble gases, that's the other name 00:07:20.900 --> 00:07:25.900 for the group 18 elements, noble gases. 00:07:26.030 --> 00:07:28.560 And they all have the very similar property 00:07:28.560 --> 00:07:29.710 of not being reactive. 00:07:29.710 --> 00:07:30.740 Why don't they react? 00:07:30.740 --> 00:07:32.600 They have filled their outermost shell. 00:07:32.600 --> 00:07:34.220 They don't find the need, they're noble, 00:07:34.220 --> 00:07:35.560 they're kind of above the fray, 00:07:35.560 --> 00:07:40.513 they don't find the need to have to react with anyone else.