0:00:00.180,0:00:02.250 - [Instructor] Ice melts[br]at 0 degrees Celsius. 0:00:02.250,0:00:03.510 But if we take something like gold, 0:00:03.510,0:00:06.870 then it'll melt only about[br]1000 degrees Celsius. 0:00:06.870,0:00:09.930 Similarly, water boils at[br]around 100 degrees Celsius. 0:00:09.930,0:00:11.580 But if we take something like nitrogen, 0:00:11.580,0:00:13.980 well, it'll boil at a very low temperature 0:00:13.980,0:00:16.650 of -200 degrees Celsius,[br]slightly about that. 0:00:16.650,0:00:19.350 But the big question is[br]why do different materials 0:00:19.350,0:00:21.720 have different melting and boiling points? 0:00:21.720,0:00:23.250 Let's find out. 0:00:23.250,0:00:24.360 Now, to answer this question, 0:00:24.360,0:00:27.150 we need to ask a much[br]more fundamental question. 0:00:27.150,0:00:29.490 What keeps stuff together? 0:00:29.490,0:00:31.710 Well, if you were to look into, you know, 0:00:31.710,0:00:32.543 if you could zoom in 0:00:32.543,0:00:34.470 and look at the molecule[br]at the atomic level, 0:00:34.470,0:00:36.360 we'll find that all[br]these atoms and molecules 0:00:36.360,0:00:38.490 are actually being[br]attracted to each other. 0:00:38.490,0:00:41.730 There is a force of attraction[br]that's keeping them together. 0:00:41.730,0:00:44.100 In fact, you've probably[br]witnessed this force of attraction 0:00:44.100,0:00:46.181 when you've seen two drops merging to form 0:00:46.181,0:00:48.570 a bigger drop, okay? 0:00:48.570,0:00:49.770 So this force of attraction 0:00:49.770,0:00:51.900 keeps all the particles together. 0:00:51.900,0:00:54.270 And turns out that this[br]force of attraction 0:00:54.270,0:00:56.820 purely depends on the types of particles. 0:00:56.820,0:00:58.830 So for example, the strength[br]of this force of attraction 0:00:58.830,0:01:00.930 between water molecules would be different 0:01:00.930,0:01:03.930 than that between gold atoms, right? 0:01:03.930,0:01:05.160 But another thing you can see 0:01:05.160,0:01:08.160 is that particles also[br]have kinetic energy. 0:01:08.160,0:01:10.530 What does that depend on? 0:01:10.530,0:01:13.230 Well, kinetic energy depends[br]purely on temperature. 0:01:13.230,0:01:14.550 In fact, temperature is a measure 0:01:14.550,0:01:16.200 of the average kinetic[br]energy of the particles. 0:01:16.200,0:01:17.033 At high temperature, 0:01:17.033,0:01:18.450 the average kinetic energy is very high. 0:01:18.450,0:01:19.350 And at low temperature, 0:01:19.350,0:01:21.030 the average kinetic energy is very low. 0:01:21.030,0:01:22.800 Kinetic energy only[br]depends on temperature. 0:01:22.800,0:01:23.700 It has nothing to do 0:01:23.700,0:01:25.830 with which particles we're dealing with. 0:01:25.830,0:01:27.690 So you can see there are[br]two things over here. 0:01:27.690,0:01:29.430 First, we have the force of attraction 0:01:29.430,0:01:31.140 that's trying to keep them together. 0:01:31.140,0:01:33.330 This purely depends on[br]the type of particle, 0:01:33.330,0:01:35.730 but it has nothing to do with temperature. 0:01:35.730,0:01:38.670 On the other hand, we have kinetic energy 0:01:38.670,0:01:41.340 that has nothing to do[br]with the particle type, 0:01:41.340,0:01:43.620 but it purely depends on temperature. 0:01:43.620,0:01:44.453 And what's interesting 0:01:44.453,0:01:46.500 is that these two are kind of opposite. 0:01:46.500,0:01:48.420 The attraction force is[br]trying to keep them together, 0:01:48.420,0:01:50.970 whereas the kinetic energy is[br]trying to make the molecules 0:01:50.970,0:01:52.380 go farther away from each other. 0:01:52.380,0:01:55.770 And it's the balance between[br]these two that decide 0:01:55.770,0:01:58.050 what the melting and the[br]boiling points would be. 0:01:58.050,0:02:01.050 So let's take a concrete[br]example to understand that. 0:02:01.050,0:02:02.730 Let's take ice at a very low temperature, 0:02:02.730,0:02:04.830 say -10, -15 degrees Celsius. 0:02:04.830,0:02:05.670 At this temperature, again, 0:02:05.670,0:02:06.960 if we were to zoom in, 0:02:06.960,0:02:08.430 we will see the atoms and molecules 0:02:08.430,0:02:10.800 all stuck together due[br]to the attractive force. 0:02:10.800,0:02:12.030 And they also have kinetic energy 0:02:12.030,0:02:13.530 that's trying to make them go apart. 0:02:13.530,0:02:14.640 However, at this temperature, 0:02:14.640,0:02:16.650 it turns out the kinetic[br]energy is very low, 0:02:16.650,0:02:18.750 so low that the force of attraction 0:02:18.750,0:02:22.080 actually locks them into[br]places giving us a solid. 0:02:22.080,0:02:23.400 And the way I like to visualize this 0:02:23.400,0:02:24.750 is by using some bar graph. 0:02:24.750,0:02:26.280 So here's the force of attraction 0:02:26.280,0:02:28.110 of the water molecules over here, 0:02:28.110,0:02:29.970 and here is the kinetic energy. 0:02:29.970,0:02:32.280 Look, the level of[br]kinetic energy is very low 0:02:32.280,0:02:33.870 relative to the force of attraction. 0:02:33.870,0:02:36.120 And as a result, you get a solid. 0:02:36.120,0:02:37.050 But now comes the big question, 0:02:37.050,0:02:39.300 what happens if we start heating it? 0:02:39.300,0:02:40.440 Why don't you pause the video 0:02:40.440,0:02:42.990 and think about what will happen[br]to the force of attraction 0:02:42.990,0:02:44.393 and the kinetic energy[br]as we start heating it? 0:02:44.393,0:02:46.860 Will it increase, decrease,[br]what happens to them? 0:02:46.860,0:02:48.513 Pause and think about it. 0:02:49.620,0:02:51.780 All right, what happens with[br]the force of attraction? 0:02:51.780,0:02:53.700 Nothing, because that only depends 0:02:53.700,0:02:54.960 on the types of atoms and molecules. 0:02:54.960,0:02:57.060 It has nothing to do with temperature. 0:02:57.060,0:02:59.460 Whereas what happens with[br]the kinetic energy, ooh, ooh! 0:02:59.460,0:03:01.530 That increases with temperature, 0:03:01.530,0:03:02.880 which means as we hit this up, 0:03:02.880,0:03:04.050 the temperature rises 0:03:04.050,0:03:06.750 and the kinetic energy[br]will start increasing. 0:03:06.750,0:03:08.070 At one particular point, 0:03:08.070,0:03:10.830 the kinetic energy of these[br]particles will be high enough 0:03:10.830,0:03:14.010 that it can partially overcome[br]the forces of attraction. 0:03:14.010,0:03:15.630 And when that happens, 0:03:15.630,0:03:17.850 the atoms and molecules will[br]no longer be locked in place. 0:03:17.850,0:03:20.070 They will start moving around. 0:03:20.070,0:03:23.250 This is when solid turns into liquid. 0:03:23.250,0:03:28.250 In our case, ice starts[br]turning into liquid water. 0:03:28.560,0:03:30.930 And this temperature at which it happens, 0:03:30.930,0:03:33.990 for water, it happens to[br]be about 0 degrees Celsius. 0:03:33.990,0:03:36.000 And that temperature where liquid turns, 0:03:36.000,0:03:37.440 sorry, solid turns into liquid, 0:03:37.440,0:03:39.660 is what we call the melting point. 0:03:39.660,0:03:43.140 So the melting point of[br]water is 0 degrees Celsius. 0:03:43.140,0:03:44.970 Now let's keep heating it up further. 0:03:44.970,0:03:46.140 What happens as we heat it up? 0:03:46.140,0:03:47.700 Again, nothing happens with[br]the force of attraction, 0:03:47.700,0:03:49.650 but the kinetic energy will keep rising. 0:03:49.650,0:03:51.240 And at one particular point, 0:03:51.240,0:03:52.290 it will be high enough 0:03:52.290,0:03:55.410 that it can fully overcome[br]the force of attraction. 0:03:55.410,0:03:56.610 And then that happens, 0:03:56.610,0:03:59.160 these molecules will now be free, 0:03:59.160,0:04:00.990 almost completely free from each other, 0:04:00.990,0:04:02.520 freely moving about. 0:04:02.520,0:04:05.730 In other words, our liquid[br]starts turning into gas, 0:04:05.730,0:04:08.220 water starts turning into steam. 0:04:08.220,0:04:09.630 So the temperature at which this happens 0:04:09.630,0:04:11.550 is what we call the boiling point. 0:04:11.550,0:04:12.930 And for water, that boiling point 0:04:12.930,0:04:16.350 happens to be at 100 degrees Celsius. 0:04:16.350,0:04:17.730 And if you further heat it, 0:04:17.730,0:04:19.230 well, the steam just gets hotter, 0:04:19.230,0:04:20.790 nothing else will happen. 0:04:20.790,0:04:22.950 So when the kinetic energy[br]is too low to overcome 0:04:22.950,0:04:25.620 any amount of attraction, we have solid. 0:04:25.620,0:04:27.090 When the kinetic energy is high enough 0:04:27.090,0:04:28.950 to partially overcome[br]the force of attraction, 0:04:28.950,0:04:29.783 we have liquid. 0:04:29.783,0:04:31.380 And when the kinetic energy is high enough 0:04:31.380,0:04:33.060 to fully overcome the force of attraction, 0:04:33.060,0:04:34.653 we get a gas. 0:04:35.760,0:04:37.380 All right, now let's[br]reverse the whole thing. 0:04:37.380,0:04:39.630 Let's cool down our gas[br]and see what happens. 0:04:39.630,0:04:41.250 Again, nothing will happen[br]to the force of attraction 0:04:41.250,0:04:42.810 because it does not depend on temperature, 0:04:42.810,0:04:44.280 but the kinetic energy will reduce 0:04:44.280,0:04:47.820 and eventually when it goes[br]below the boiling point, look! 0:04:47.820,0:04:49.920 It will no longer be[br]able to fully overcome 0:04:49.920,0:04:50.820 the force of attraction, 0:04:50.820,0:04:54.090 which means the gas will turn into liquid. 0:04:54.090,0:04:55.770 We call this condensation, 0:04:55.770,0:04:57.720 and this point is called[br]the condensation point. 0:04:57.720,0:04:59.370 And you can clearly see[br]the condensation point 0:04:59.370,0:05:01.560 is the same thing as the boiling point. 0:05:01.560,0:05:03.210 And we've seen this before. 0:05:03.210,0:05:05.040 For example, when you,[br]you know, hold a plate 0:05:05.040,0:05:06.390 over, say boiling water, 0:05:06.390,0:05:08.700 we see liquid drops, that's condensation. 0:05:08.700,0:05:10.890 The steam over here has temperature 0:05:10.890,0:05:12.540 lower than the condensation point, 0:05:12.540,0:05:13.680 lower than 100 degrees Celsius 0:05:13.680,0:05:15.960 so it condenses into liquid water. 0:05:15.960,0:05:18.180 And that's why you see[br]the drops over there. 0:05:18.180,0:05:19.080 Okay, and what happens 0:05:19.080,0:05:21.540 if we were to reduce the[br]temperature even more? 0:05:21.540,0:05:24.150 Well, again, the kinetic[br]energy will keep reducing. 0:05:24.150,0:05:27.030 And when it's below the[br]melting point, look! 0:05:27.030,0:05:28.740 It will no longer be able to overcome 0:05:28.740,0:05:30.480 any force of attraction, 0:05:30.480,0:05:33.330 which means the liquid[br]will turn back into solid. 0:05:33.330,0:05:35.580 We call this the freezing point. 0:05:35.580,0:05:36.954 And you can see the freezing point 0:05:36.954,0:05:39.870 is the same as the melting point. 0:05:39.870,0:05:41.845 And therefore, when[br]liquid water, you know, 0:05:41.845,0:05:44.070 is below 0 degrees Celsius, 0:05:44.070,0:05:46.740 it freezes into ice. 0:05:46.740,0:05:48.720 Okay, so the key thing[br]that we see over here 0:05:48.720,0:05:50.790 is that the boiling point[br]and the melting point 0:05:50.790,0:05:53.440 depends a lot on the force[br]of attraction, right? 0:05:53.440,0:05:55.350 Now, here's a question: 0:05:55.350,0:05:58.200 What if we consider a material like gold? 0:05:58.200,0:05:59.910 Well, it turns out for gold, 0:05:59.910,0:06:02.610 the force of attraction is much higher 0:06:02.610,0:06:03.930 than that of water. 0:06:03.930,0:06:04.800 Now, actually, the attraction 0:06:04.800,0:06:06.480 is much higher in gold compared to water. 0:06:06.480,0:06:08.760 So the graph should be[br]much higher over here. 0:06:08.760,0:06:09.810 But don't worry about that. 0:06:09.810,0:06:12.870 But this means now the kinetic[br]energy needed to partially 0:06:12.870,0:06:15.000 and fully overcome the force of attraction 0:06:15.000,0:06:16.830 would be much higher than before. 0:06:16.830,0:06:19.800 And as a result, the freezing[br]point or the melting point 0:06:19.800,0:06:23.280 and the boiling point would[br]be much higher than before. 0:06:23.280,0:06:26.190 For gold, it turns out to be, you know, 0:06:26.190,0:06:27.630 about 1000 degrees Celsius 0:06:27.630,0:06:30.270 and about like close to[br]3000 degrees Celsius. 0:06:30.270,0:06:32.041 That's why for gold, 0:06:32.041,0:06:34.560 you need a much, much higher temperature 0:06:34.560,0:06:36.300 for it to melt. 0:06:36.300,0:06:37.680 Okay, what about nitrogen? 0:06:37.680,0:06:38.670 Well, it terms for nitrogen, 0:06:38.670,0:06:40.950 the force of attraction[br]is much, much lower. 0:06:40.950,0:06:43.470 And therefore, the melting[br]point and the boiling points 0:06:43.470,0:06:44.880 would be much lower. 0:06:44.880,0:06:46.279 And that's why it boils 0:06:46.279,0:06:47.940 at a much lower temperature 0:06:47.940,0:06:50.610 of -196 degrees Celsius actually. 0:06:50.610,0:06:51.810 That's why at room temperature, 0:06:51.810,0:06:53.730 nitrogen is a gas. 0:06:53.730,0:06:55.560 So long story short, 0:06:55.560,0:06:57.600 the temperature at[br]which the kinetic energy 0:06:57.600,0:06:59.760 can partially overcome[br]the force of attraction 0:06:59.760,0:07:02.220 is what we call the melting[br]or the freezing point. 0:07:02.220,0:07:05.100 That's when you have a phase[br]change from solid to liquid 0:07:05.100,0:07:07.200 or liquid to solid if[br]you're cooling it down. 0:07:07.200,0:07:09.270 And similarly, the temperature[br]at which the kinetic energy 0:07:09.270,0:07:12.112 is high enough to fully overcome[br]the force of attraction, 0:07:12.112,0:07:14.310 that's what we call the boiling point. 0:07:14.310,0:07:16.410 That's when you get a phase[br]change from liquid to gas, 0:07:16.410,0:07:19.170 or again, if you're cooling[br]it down, from gas to liquid. 0:07:19.170,0:07:21.450 And look, since these temperatures 0:07:21.450,0:07:23.370 purely depend upon how strong or weak 0:07:23.370,0:07:26.430 the attractive force is and that, in turn, 0:07:26.430,0:07:29.310 depends upon which types of[br]particles we are dealing with, 0:07:29.310,0:07:31.290 types of atoms and molecules[br]we're dealing with. 0:07:31.290,0:07:33.420 That's the reason why the[br]boiling points and melting points 0:07:33.420,0:07:35.490 of different particles,[br]different substances 0:07:35.490,0:07:36.873 would be different.