1 00:00:00,180 --> 00:00:02,250 - [Instructor] Ice melts at 0 degrees Celsius. 2 00:00:02,250 --> 00:00:03,510 But if we take something like gold, 3 00:00:03,510 --> 00:00:06,870 then it'll melt only about 1000 degrees Celsius. 4 00:00:06,870 --> 00:00:09,930 Similarly, water boils at around 100 degrees Celsius. 5 00:00:09,930 --> 00:00:11,580 But if we take something like nitrogen, 6 00:00:11,580 --> 00:00:13,980 well, it'll boil at a very low temperature 7 00:00:13,980 --> 00:00:16,650 of -200 degrees Celsius, slightly about that. 8 00:00:16,650 --> 00:00:19,350 But the big question is why do different materials 9 00:00:19,350 --> 00:00:21,720 have different melting and boiling points? 10 00:00:21,720 --> 00:00:23,250 Let's find out. 11 00:00:23,250 --> 00:00:24,360 Now, to answer this question, 12 00:00:24,360 --> 00:00:27,150 we need to ask a much more fundamental question. 13 00:00:27,150 --> 00:00:29,490 What keeps stuff together? 14 00:00:29,490 --> 00:00:31,710 Well, if you were to look into, you know, 15 00:00:31,710 --> 00:00:32,543 if you could zoom in 16 00:00:32,543 --> 00:00:34,470 and look at the molecule at the atomic level, 17 00:00:34,470 --> 00:00:36,360 we'll find that all these atoms and molecules 18 00:00:36,360 --> 00:00:38,490 are actually being attracted to each other. 19 00:00:38,490 --> 00:00:41,730 There is a force of attraction that's keeping them together. 20 00:00:41,730 --> 00:00:44,100 In fact, you've probably witnessed this force of attraction 21 00:00:44,100 --> 00:00:46,181 when you've seen two drops merging to form 22 00:00:46,181 --> 00:00:48,570 a bigger drop, okay? 23 00:00:48,570 --> 00:00:49,770 So this force of attraction 24 00:00:49,770 --> 00:00:51,900 keeps all the particles together. 25 00:00:51,900 --> 00:00:54,270 And turns out that this force of attraction 26 00:00:54,270 --> 00:00:56,820 purely depends on the types of particles. 27 00:00:56,820 --> 00:00:58,830 So for example, the strength of this force of attraction 28 00:00:58,830 --> 00:01:00,930 between water molecules would be different 29 00:01:00,930 --> 00:01:03,930 than that between gold atoms, right? 30 00:01:03,930 --> 00:01:05,160 But another thing you can see 31 00:01:05,160 --> 00:01:08,160 is that particles also have kinetic energy. 32 00:01:08,160 --> 00:01:10,530 What does that depend on? 33 00:01:10,530 --> 00:01:13,230 Well, kinetic energy depends purely on temperature. 34 00:01:13,230 --> 00:01:14,550 In fact, temperature is a measure 35 00:01:14,550 --> 00:01:16,200 of the average kinetic energy of the particles. 36 00:01:16,200 --> 00:01:17,033 At high temperature, 37 00:01:17,033 --> 00:01:18,450 the average kinetic energy is very high. 38 00:01:18,450 --> 00:01:19,350 And at low temperature, 39 00:01:19,350 --> 00:01:21,030 the average kinetic energy is very low. 40 00:01:21,030 --> 00:01:22,800 Kinetic energy only depends on temperature. 41 00:01:22,800 --> 00:01:23,700 It has nothing to do 42 00:01:23,700 --> 00:01:25,830 with which particles we're dealing with. 43 00:01:25,830 --> 00:01:27,690 So you can see there are two things over here. 44 00:01:27,690 --> 00:01:29,430 First, we have the force of attraction 45 00:01:29,430 --> 00:01:31,140 that's trying to keep them together. 46 00:01:31,140 --> 00:01:33,330 This purely depends on the type of particle, 47 00:01:33,330 --> 00:01:35,730 but it has nothing to do with temperature. 48 00:01:35,730 --> 00:01:38,670 On the other hand, we have kinetic energy 49 00:01:38,670 --> 00:01:41,340 that has nothing to do with the particle type, 50 00:01:41,340 --> 00:01:43,620 but it purely depends on temperature. 51 00:01:43,620 --> 00:01:44,453 And what's interesting 52 00:01:44,453 --> 00:01:46,500 is that these two are kind of opposite. 53 00:01:46,500 --> 00:01:48,420 The attraction force is trying to keep them together, 54 00:01:48,420 --> 00:01:50,970 whereas the kinetic energy is trying to make the molecules 55 00:01:50,970 --> 00:01:52,380 go farther away from each other. 56 00:01:52,380 --> 00:01:55,770 And it's the balance between these two that decide 57 00:01:55,770 --> 00:01:58,050 what the melting and the boiling points would be. 58 00:01:58,050 --> 00:02:01,050 So let's take a concrete example to understand that. 59 00:02:01,050 --> 00:02:02,730 Let's take ice at a very low temperature, 60 00:02:02,730 --> 00:02:04,830 say -10, -15 degrees Celsius. 61 00:02:04,830 --> 00:02:05,670 At this temperature, again, 62 00:02:05,670 --> 00:02:06,960 if we were to zoom in, 63 00:02:06,960 --> 00:02:08,430 we will see the atoms and molecules 64 00:02:08,430 --> 00:02:10,800 all stuck together due to the attractive force. 65 00:02:10,800 --> 00:02:12,030 And they also have kinetic energy 66 00:02:12,030 --> 00:02:13,530 that's trying to make them go apart. 67 00:02:13,530 --> 00:02:14,640 However, at this temperature, 68 00:02:14,640 --> 00:02:16,650 it turns out the kinetic energy is very low, 69 00:02:16,650 --> 00:02:18,750 so low that the force of attraction 70 00:02:18,750 --> 00:02:22,080 actually locks them into places giving us a solid. 71 00:02:22,080 --> 00:02:23,400 And the way I like to visualize this 72 00:02:23,400 --> 00:02:24,750 is by using some bar graph. 73 00:02:24,750 --> 00:02:26,280 So here's the force of attraction 74 00:02:26,280 --> 00:02:28,110 of the water molecules over here, 75 00:02:28,110 --> 00:02:29,970 and here is the kinetic energy. 76 00:02:29,970 --> 00:02:32,280 Look, the level of kinetic energy is very low 77 00:02:32,280 --> 00:02:33,870 relative to the force of attraction. 78 00:02:33,870 --> 00:02:36,120 And as a result, you get a solid. 79 00:02:36,120 --> 00:02:37,050 But now comes the big question, 80 00:02:37,050 --> 00:02:39,300 what happens if we start heating it? 81 00:02:39,300 --> 00:02:40,440 Why don't you pause the video 82 00:02:40,440 --> 00:02:42,990 and think about what will happen to the force of attraction 83 00:02:42,990 --> 00:02:44,393 and the kinetic energy as we start heating it? 84 00:02:44,393 --> 00:02:46,860 Will it increase, decrease, what happens to them? 85 00:02:46,860 --> 00:02:48,513 Pause and think about it. 86 00:02:49,620 --> 00:02:51,780 All right, what happens with the force of attraction? 87 00:02:51,780 --> 00:02:53,700 Nothing, because that only depends 88 00:02:53,700 --> 00:02:54,960 on the types of atoms and molecules. 89 00:02:54,960 --> 00:02:57,060 It has nothing to do with temperature. 90 00:02:57,060 --> 00:02:59,460 Whereas what happens with the kinetic energy, ooh, ooh! 91 00:02:59,460 --> 00:03:01,530 That increases with temperature, 92 00:03:01,530 --> 00:03:02,880 which means as we hit this up, 93 00:03:02,880 --> 00:03:04,050 the temperature rises 94 00:03:04,050 --> 00:03:06,750 and the kinetic energy will start increasing. 95 00:03:06,750 --> 00:03:08,070 At one particular point, 96 00:03:08,070 --> 00:03:10,830 the kinetic energy of these particles will be high enough 97 00:03:10,830 --> 00:03:14,010 that it can partially overcome the forces of attraction. 98 00:03:14,010 --> 00:03:15,630 And when that happens, 99 00:03:15,630 --> 00:03:17,850 the atoms and molecules will no longer be locked in place. 100 00:03:17,850 --> 00:03:20,070 They will start moving around. 101 00:03:20,070 --> 00:03:23,250 This is when solid turns into liquid. 102 00:03:23,250 --> 00:03:28,250 In our case, ice starts turning into liquid water. 103 00:03:28,560 --> 00:03:30,930 And this temperature at which it happens, 104 00:03:30,930 --> 00:03:33,990 for water, it happens to be about 0 degrees Celsius. 105 00:03:33,990 --> 00:03:36,000 And that temperature where liquid turns, 106 00:03:36,000 --> 00:03:37,440 sorry, solid turns into liquid, 107 00:03:37,440 --> 00:03:39,660 is what we call the melting point. 108 00:03:39,660 --> 00:03:43,140 So the melting point of water is 0 degrees Celsius. 109 00:03:43,140 --> 00:03:44,970 Now let's keep heating it up further. 110 00:03:44,970 --> 00:03:46,140 What happens as we heat it up? 111 00:03:46,140 --> 00:03:47,700 Again, nothing happens with the force of attraction, 112 00:03:47,700 --> 00:03:49,650 but the kinetic energy will keep rising. 113 00:03:49,650 --> 00:03:51,240 And at one particular point, 114 00:03:51,240 --> 00:03:52,290 it will be high enough 115 00:03:52,290 --> 00:03:55,410 that it can fully overcome the force of attraction. 116 00:03:55,410 --> 00:03:56,610 And then that happens, 117 00:03:56,610 --> 00:03:59,160 these molecules will now be free, 118 00:03:59,160 --> 00:04:00,990 almost completely free from each other, 119 00:04:00,990 --> 00:04:02,520 freely moving about. 120 00:04:02,520 --> 00:04:05,730 In other words, our liquid starts turning into gas, 121 00:04:05,730 --> 00:04:08,220 water starts turning into steam. 122 00:04:08,220 --> 00:04:09,630 So the temperature at which this happens 123 00:04:09,630 --> 00:04:11,550 is what we call the boiling point. 124 00:04:11,550 --> 00:04:12,930 And for water, that boiling point 125 00:04:12,930 --> 00:04:16,350 happens to be at 100 degrees Celsius. 126 00:04:16,350 --> 00:04:17,730 And if you further heat it, 127 00:04:17,730 --> 00:04:19,230 well, the steam just gets hotter, 128 00:04:19,230 --> 00:04:20,790 nothing else will happen. 129 00:04:20,790 --> 00:04:22,950 So when the kinetic energy is too low to overcome 130 00:04:22,950 --> 00:04:25,620 any amount of attraction, we have solid. 131 00:04:25,620 --> 00:04:27,090 When the kinetic energy is high enough 132 00:04:27,090 --> 00:04:28,950 to partially overcome the force of attraction, 133 00:04:28,950 --> 00:04:29,783 we have liquid. 134 00:04:29,783 --> 00:04:31,380 And when the kinetic energy is high enough 135 00:04:31,380 --> 00:04:33,060 to fully overcome the force of attraction, 136 00:04:33,060 --> 00:04:34,653 we get a gas. 137 00:04:35,760 --> 00:04:37,380 All right, now let's reverse the whole thing. 138 00:04:37,380 --> 00:04:39,630 Let's cool down our gas and see what happens. 139 00:04:39,630 --> 00:04:41,250 Again, nothing will happen to the force of attraction 140 00:04:41,250 --> 00:04:42,810 because it does not depend on temperature, 141 00:04:42,810 --> 00:04:44,280 but the kinetic energy will reduce 142 00:04:44,280 --> 00:04:47,820 and eventually when it goes below the boiling point, look! 143 00:04:47,820 --> 00:04:49,920 It will no longer be able to fully overcome 144 00:04:49,920 --> 00:04:50,820 the force of attraction, 145 00:04:50,820 --> 00:04:54,090 which means the gas will turn into liquid. 146 00:04:54,090 --> 00:04:55,770 We call this condensation, 147 00:04:55,770 --> 00:04:57,720 and this point is called the condensation point. 148 00:04:57,720 --> 00:04:59,370 And you can clearly see the condensation point 149 00:04:59,370 --> 00:05:01,560 is the same thing as the boiling point. 150 00:05:01,560 --> 00:05:03,210 And we've seen this before. 151 00:05:03,210 --> 00:05:05,040 For example, when you, you know, hold a plate 152 00:05:05,040 --> 00:05:06,390 over, say boiling water, 153 00:05:06,390 --> 00:05:08,700 we see liquid drops, that's condensation. 154 00:05:08,700 --> 00:05:10,890 The steam over here has temperature 155 00:05:10,890 --> 00:05:12,540 lower than the condensation point, 156 00:05:12,540 --> 00:05:13,680 lower than 100 degrees Celsius 157 00:05:13,680 --> 00:05:15,960 so it condenses into liquid water. 158 00:05:15,960 --> 00:05:18,180 And that's why you see the drops over there. 159 00:05:18,180 --> 00:05:19,080 Okay, and what happens 160 00:05:19,080 --> 00:05:21,540 if we were to reduce the temperature even more? 161 00:05:21,540 --> 00:05:24,150 Well, again, the kinetic energy will keep reducing. 162 00:05:24,150 --> 00:05:27,030 And when it's below the melting point, look! 163 00:05:27,030 --> 00:05:28,740 It will no longer be able to overcome 164 00:05:28,740 --> 00:05:30,480 any force of attraction, 165 00:05:30,480 --> 00:05:33,330 which means the liquid will turn back into solid. 166 00:05:33,330 --> 00:05:35,580 We call this the freezing point. 167 00:05:35,580 --> 00:05:36,954 And you can see the freezing point 168 00:05:36,954 --> 00:05:39,870 is the same as the melting point. 169 00:05:39,870 --> 00:05:41,845 And therefore, when liquid water, you know, 170 00:05:41,845 --> 00:05:44,070 is below 0 degrees Celsius, 171 00:05:44,070 --> 00:05:46,740 it freezes into ice. 172 00:05:46,740 --> 00:05:48,720 Okay, so the key thing that we see over here 173 00:05:48,720 --> 00:05:50,790 is that the boiling point and the melting point 174 00:05:50,790 --> 00:05:53,440 depends a lot on the force of attraction, right? 175 00:05:53,440 --> 00:05:55,350 Now, here's a question: 176 00:05:55,350 --> 00:05:58,200 What if we consider a material like gold? 177 00:05:58,200 --> 00:05:59,910 Well, it turns out for gold, 178 00:05:59,910 --> 00:06:02,610 the force of attraction is much higher 179 00:06:02,610 --> 00:06:03,930 than that of water. 180 00:06:03,930 --> 00:06:04,800 Now, actually, the attraction 181 00:06:04,800 --> 00:06:06,480 is much higher in gold compared to water. 182 00:06:06,480 --> 00:06:08,760 So the graph should be much higher over here. 183 00:06:08,760 --> 00:06:09,810 But don't worry about that. 184 00:06:09,810 --> 00:06:12,870 But this means now the kinetic energy needed to partially 185 00:06:12,870 --> 00:06:15,000 and fully overcome the force of attraction 186 00:06:15,000 --> 00:06:16,830 would be much higher than before. 187 00:06:16,830 --> 00:06:19,800 And as a result, the freezing point or the melting point 188 00:06:19,800 --> 00:06:23,280 and the boiling point would be much higher than before. 189 00:06:23,280 --> 00:06:26,190 For gold, it turns out to be, you know, 190 00:06:26,190 --> 00:06:27,630 about 1000 degrees Celsius 191 00:06:27,630 --> 00:06:30,270 and about like close to 3000 degrees Celsius. 192 00:06:30,270 --> 00:06:32,041 That's why for gold, 193 00:06:32,041 --> 00:06:34,560 you need a much, much higher temperature 194 00:06:34,560 --> 00:06:36,300 for it to melt. 195 00:06:36,300 --> 00:06:37,680 Okay, what about nitrogen? 196 00:06:37,680 --> 00:06:38,670 Well, it terms for nitrogen, 197 00:06:38,670 --> 00:06:40,950 the force of attraction is much, much lower. 198 00:06:40,950 --> 00:06:43,470 And therefore, the melting point and the boiling points 199 00:06:43,470 --> 00:06:44,880 would be much lower. 200 00:06:44,880 --> 00:06:46,279 And that's why it boils 201 00:06:46,279 --> 00:06:47,940 at a much lower temperature 202 00:06:47,940 --> 00:06:50,610 of -196 degrees Celsius actually. 203 00:06:50,610 --> 00:06:51,810 That's why at room temperature, 204 00:06:51,810 --> 00:06:53,730 nitrogen is a gas. 205 00:06:53,730 --> 00:06:55,560 So long story short, 206 00:06:55,560 --> 00:06:57,600 the temperature at which the kinetic energy 207 00:06:57,600 --> 00:06:59,760 can partially overcome the force of attraction 208 00:06:59,760 --> 00:07:02,220 is what we call the melting or the freezing point. 209 00:07:02,220 --> 00:07:05,100 That's when you have a phase change from solid to liquid 210 00:07:05,100 --> 00:07:07,200 or liquid to solid if you're cooling it down. 211 00:07:07,200 --> 00:07:09,270 And similarly, the temperature at which the kinetic energy 212 00:07:09,270 --> 00:07:12,112 is high enough to fully overcome the force of attraction, 213 00:07:12,112 --> 00:07:14,310 that's what we call the boiling point. 214 00:07:14,310 --> 00:07:16,410 That's when you get a phase change from liquid to gas, 215 00:07:16,410 --> 00:07:19,170 or again, if you're cooling it down, from gas to liquid. 216 00:07:19,170 --> 00:07:21,450 And look, since these temperatures 217 00:07:21,450 --> 00:07:23,370 purely depend upon how strong or weak 218 00:07:23,370 --> 00:07:26,430 the attractive force is and that, in turn, 219 00:07:26,430 --> 00:07:29,310 depends upon which types of particles we are dealing with, 220 00:07:29,310 --> 00:07:31,290 types of atoms and molecules we're dealing with. 221 00:07:31,290 --> 00:07:33,420 That's the reason why the boiling points and melting points 222 00:07:33,420 --> 00:07:35,490 of different particles, different substances 223 00:07:35,490 --> 00:07:36,873 would be different.